European Union foreign
ministers have agreed to impose sanctions on Ukrainian officials
"responsible for violence and excessive force".
In a statement, they said targeted sanctions including asset freezes and visa bans would be introduced "as a matter of urgency".
At least 21 anti-government protesters died in clashes in Kiev on Thursday.
Officials said that one policeman had also died and that 67 police had been captured by protesters.
"No circumstances can justify the repression we are currently witnessing," the statement from EU foreign ministers said.
EU foreign policy chief Catherine Ashton said the "prime responsibility" to get talks between the two sides under way lay with President Viktor Yanukovych.
Tempers frayed in parliament, leading to a brawl between MPs
Implementation of the measures "will be taken forward in light of developments in Ukraine", she added.
The EU has until now refrained from imposing sanctions on Ukraine, preferring to emphasise dialogue and compromise.
The US state department had already announced visa bans on 20
members of the Ukrainian government but has not provided any names. Live rounds
Ukraine's health ministry says 75 people have now died and 571 have been injured in violence since Tuesday.
At least 21 protesters were killed by security forces in Kiev on Thursday following the breakdown of a truce the previous day.
Several dead bodies of protesters killed on Thursday were brought to Independence Square, the focal point of the protests, the BBC's Duncan Crawford in Kiev reports.
Assembled crowds shouted "martyrs!" and "heroes!", with some protesters in tears, our correspondent adds.
Witnesses have told the BBC that some of those killed on Thursday died as a result of single gunshot wounds, typical of sniper fire.
Video footage has emerged apparently showing snipers firing on demonstrators who had been trying to retake their protest camp in Independence Square.
The authorities said that one policeman had died and that 67 police had been captured by protesters.
Amateur footage appears to show police hostages -
wearing blue uniforms with black collars - being kept in a line by men
in plain clothes in Kiev
Witnesses reported live rounds, petrol bombs and water cannon being used at Independence Square during Thursday morning's clashes.
Some armed demonstrators were also reported to be firing towards security forces.
Gunshots pierced the windows of rooms at the Ukraine Hotel, which is serving as the base for all foreign media in Kiev, including the BBC.
Earlier, several dozen protesters were using the lobby as a triage centre for the wounded, and a priest arrived, says the BBC's Kevin Bishop, at the scene.
The atmosphere remained tense as night fell on Independence Square, the main protest camp in Kiev
Demonstrators continued to build barricades on the square
A vigil has been held for protesters killed in clashes with security forces
A video still released earlier shows a riot policeman standing next to a sniper firing in Kiev
Protesters are seen escorting policemen in Kiev on Thursday. Officials said 67 officers had been captured.
A statement on the presidential website blamed the opposition for starting the violence, saying the "calls for a truce and dialogue were nothing but a way of playing for time to mobilise and arm militants from Maidan [Independence Square]".
MPs assembled for a session of parliament on Thursday afternoon voted to condemn the recent violence. They also called for the use of weapons against protesters to be banned, and for troops and police deployed against them to be withdrawn.
The session was attended by 239 out of 450 MPs, most of them from opposition parties.
Earlier the foreign ministers of France, Poland and Germany conducted several hours of discussions with Mr Yanukovych on a "roadmap towards a political solution" before going on to talks with opposition leaders.
They returned for another meeting with Mr Yanukovych on Thursday evening.
Polish Prime Minister Donald Tusk said Mr Yanukovych had expressed willingness to hold early elections this year.
The protests first erupted in November when President Yanukovych rejected a landmark association and trade deal with the EU in favour of closer ties with Russia.
Since then, the protests have spread across Ukraine, with the demonstrators' main demand being snap presidential and parliamentary elections.
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